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Dynamic SIMS (DSIMS) provides semi-quantitative information on the elemental composition of the sample surface region from a few nm to several hundreds of microns in depth. The detection sensitivity of the technique is in the ppm - ppb range for all elements in the periodic table.

In Dynamic SIMS a primary ion beam of energy 0.5keV - 20keV is used to sputter-remove successive layers of the sample in a well-defined area ranging in size from typically 1mm x 1mm to 10 x 10 microns. The emitted positive and negative secondary ions are collected and mass analysed in a mass spectrometer.  The secondary ion currents are representative of the sample composition and with appropriate use of standard samples can be used to produce quantitative information on the lateral and depth distribution of major elements, dopants and impurities in any solid material.

The primary beam can be O2+, O-, Cs+, or Ar+.  O2+ is used for the detection of electropositive species and Cs+ for electronegative species.  For example, analysis for boron and sodium in silicon would be carried out with O2+ while detection of oxygen and carbon in GaAs would require Cs+.

Several types of analytical information can be generated, including :-

Mass spectrum - by scanning the mass spectrometer over its mass range (> 500amu) elemental and molecular information is obtained from an area of the sample.

Depth profile - monitoring several elemental or molecular species with time while continuously sputtering a well defined sample area produces a plot of secondary ion intensity vs. time which is processed to give concentration vs. depth plots.

2D and 3D images - monitoring several species while the primary beam is rastered over the sample area produces chemical images of the surface. Continual acquisition of images with depth can also provide 3D information including retrospective depth profiling and sectioning.

Line scans - the primary beam can be scanned across surface features to produce line scans to identify distinct chemical boundaries.